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Beilstein J. Org. Chem. 2019, 15, 1786–1794, doi:10.3762/bjoc.15.172
Graphical Abstract
Scheme 1: Oxidation of 3-pheny-1-propanol (1a) with N-chlorosuccinimide (NCS) in the presence of (2,2,6,6-tet...
Scheme 2: Hypothesized pathways for the TEMPO-assisted oxidation of alcohols in a) basic or b) acidic reactio...
Scheme 3: TEMPO-assisted oxidation of 3-pheny-1-propanol (1a) under mechanical activation conditions. aPercen...
Scheme 4: Scope of primary alcohol oxidation under mechanical activation conditions. aAll yields refer to iso...
Scheme 5: Proposed mechanism for the oxidation of benzylic alcohols 6a and 7a under mechanochemical condition...
Scheme 6: Scope of secondary alcohols in the oxidation under mechanical activation conditions. aAll yields re...
Scheme 7: Possible mechanism for the TEMPO-mediated oxidation of primary and secondary alcohols by using NaOC...
Beilstein J. Org. Chem. 2017, 13, 2049–2055, doi:10.3762/bjoc.13.202
Scheme 1: TEMPO-catalysed aerobic oxidative procedures of alcohols. a) Anelli–Montanari protocol: NaOCl (1.25...
Scheme 2: TEMPO-assisted oxidation of 4-nitrobenzylic alcohol under mechanical activation conditions [65].
Scheme 3: Scope of primary alcohols in oxidation under ambient air.
Scheme 4: Scope of secondary alcohols in oxidation under ambient air.